Polarized photoluminescence excitation spectroscopy of single-walled carbon nanotubes.

نویسندگان

  • J Lefebvre
  • P Finnie
چکیده

The polarized photoluminescence excitation spectra of twenty-five single-walled carbon nanotube species are reported. For light polarized along the nanotube axis, the main absorption resonance at E22 shows sidebands attributed to phonon assisted absorption. Sidebands to E11 have a diameter dependent energy and are assigned to excited excitonic states. Along with longitudinal excitations, several transverse excitations are identified. The transverse E12 resonance has a specific family pattern with energy close to E22. Comparison with theory provides an estimate of the strength of the Coulomb interaction.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Cross-polarized optical absorption of single-walled nanotubes probed by polarized photoluminescence excitation spectroscopy

Cross-polarized absorption peaks of isolated single-walled carbon nanotubes were observed by a polarized photoluminescence excitation (PLE) spectroscopy. Using a simple theory for PL anisotropy, the observed PLE spectra are decomposed into ‘pure’ components of the photoexcitation for incident light polarized parallel and perpendicular to the SWNT axis. For several (n, m) SWNTs, distinct peaks c...

متن کامل

Exciton transition energy in photoluminescence of single-walled carbon nanotubes

Photoluminescence excitation (PLE) spectroscopy of single-walled carbon nanotubes (SWNTs) has been extensively studied for characterization of their unique electronic properties due to the one-dimensionality. The precise evaluation of exciton transition energy is essential for experimental assignments of optical absorption, photoluminescence, and resonant Raman scatterings. Here, several experi...

متن کامل

Near-field imaging and spectroscopy of electronic states in single-walled carbon nanotubes

Near-field photoluminescence spectroscopy was used to study the electronic properties of semiconducting Single-Walled Carbon Nanotubes in different environments. A sharp laser-illuminated metal tip was raster scanned over the sample and served as a strongly confined excitation source. We observed localization of photoluminescence and variations of emission energies along nanotubes on a length s...

متن کامل

Exciton localization of single-walled carbon nanotubes revealed by femtosecond excitation correlation spectroscopy.

Photoluminescence (PL) dynamics in single-walled carbon nanotubes (SWNTs) has been studied by the femtosecond excitation correlation method with a 150 fs time resolution. The SWNT samples were synthesized by different methods and suspended in gelatin films or D2O solutions. The PL dynamics of SWNTs depends on the local environment surrounding the SWNTs rather than the synthesis methods. The ver...

متن کامل

Exciton dynamics of single-walled carbon nanotubes revealed by femtosecond excitation correlation spectroscopy: exciton localization

Photoluminescence (PL) dynamics in single-walled carbon nanotubes (SWNTs) has been studied by the femtosecond excitation correlation method with a 150 fs time resolution. The SWNT samples were synthesized by different methods and suspended in gelatin films or D2O solutions. The PL dynamics of SWNTs depends on the local environment surrounding the SWNTs rather than the synthesis methods. The ver...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Physical review letters

دوره 98 16  شماره 

صفحات  -

تاریخ انتشار 2007